N′-(Adamantan-2-yl­idene)thio­phene-2-carbohydrazide

نویسندگان

  • Adnan A. Kadi
  • Amer M. Alanzi
  • Ali A. El-Emam
  • Seik Weng Ng
  • Edward R. T. Tiekink
چکیده

In the title mol-ecule, C(15)H(18)N(2)OS, a small twist is noted, with the dihedral angle between the central carbohydrazone residue (r.m.s. deviation = 0.029 Å) and the thio-phene ring being 12.47 (10)°. The syn arrangement of the amide H and carbonyl O atoms allows for the formation of centrosymmetric dimers via N-H⋯O hydrogen bonds. These are linked in the three-dimensional structure by C-H⋯π inter-actions. The thio-phene ring is disordered over two co-planar orientations, the major component having a site-occupancy factor of 0.833 (2).

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011